Growth, optical, spectral, thermal and mechanical investigations of organic NLO crystal cis-2, 6-bis(4-chlorophenyl)-3, 3-dimethylpiperidin-4-one

Mohanraj V
P.G. & Research Department of Chemistry, Government Arts College (Autonomous), Coimbatore - 641 018, India.
Ilango S.S.
P.G. & Research Department of Chemistry, Government Arts College (Autonomous), Coimbatore - 641 018, India.
Ponnuswamy S
P.G. & Research Department of Chemistry, Government Arts College (Autonomous), Coimbatore - 641 018, India.

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Abstract

The single crystal of cis-2,6-bis(4-chlorophenyl)-3,3-dimethylpiperidin-4-one (4C3DMPO) has been grown using a slow evaporation technique. 4C3DMPO is a non-centrosymmetric crystal which crystallizes in the orthorhombic system with space group Pna21. Benzene is used as a solvent for the crystal growth based on solubility studies. The mechanical studies, using microhardness methods, have also been carried out. The compound is characterised using UV, FT-IR and NMR spectral studies. Furthermore, the thermal stability of the crystal is established by TG/DTA. The nonlinear optical studies (SHG) of the crystal have been determined using the Kurtz and Perry powder technique and the activity observed is 2.5 times greater than that of KDP.

Keywords

  • Crystal growth,
  • Solubility,
  • Microhardness,
  • Thermal properties

References

  1. Williams D. Nonlinear Optical Properties of Organic and Polymeric Materials. ACS SymposiumSeries. 1983;233.
  2. Aggarwal M, Choi J, Wang W, Bhat K, Lal R, Shields AD, Penn BG, Frazier DO. Solution growth of a novel nonlinear optical material: L-histidine tetrafluoroborate. Journal of Crystal Growth. 1999;204(1-2).
  3. Frazier CC, Chauchard EA, Lee CH, Cockerham MP. Second-harmonic generation in aromatic organic compounds. Journal of the Optical Society of America B. 1987;4(11).
  4. Deepthy A, Bhat H. Growth and characterization of ferroelectric glycine phosphite single crystals. Journal of Crystal Growth. 2001;226(2-3).
  5. Ponnuswamy S, Mohanraj V, Ilango S, Thenmozhi M, Ponnuswamy M. Growth, thermal, mechanical, structural and optical properties of organic NLO crystals of novel cis-2,6-bis(2-chlorophenyl)-3,3-dimethylpiperidin-4-one. Journal of Molecular Structure. 2015;1081.
  6. Ponnuswamy S, Mohanraj V, Sakthivel P, Chandramohan A. Growth, thermal and optical properties of cis-2,6-diphenyl-3-isopropylpiperidin-4-one – A new class of organic NLO material. Optik. 2014;125(19).
  7. Manivannan S. Synthesis, crystal growth, structural and optical properties of an organic NLO material. Journal of Crystal Growth. 2004;262(1-4).
  8. Vasudevan V, Ramesh Babu R, Ramamurthi K. Surface topography and optical studies on polystyrene (PS) coated l-Lysine monohydrochloride dihydrate (L-LMHCl) single crystals. Materials Letters. 2012;68.
  9. Vizhi RE, Kalainathan S. Growth and characterization of a new organic NLO material: 1,3 Diglycinyl thiourea. Materials Letters. 2008;62(4-5).
  10. Vijayan N, Ramesh Babu R, Gopalakrishnan R, Ramasamy P. Some studies on the growth and characterization of organic nonlinear optical acetoacetanilide single crystals. Journal of Crystal Growth. 2004;267(3-4).
  11. Long NJ. Organometallic Compounds for Nonlinear Optics—The Search for En-light-enment!. Angewandte Chemie International Edition in English. 1995;34(1).
  12. Ilango SS, Ponnuswamy S, Gayathri P, Thiruvalluvar A, Butcher RJ. r-2,c-6-Bis(4-chlorophenyl)-c-3,t-3-dimethylpiperidin-4-one. Acta Crystallographica Section E Structure Reports Online. 2008;64(12).
  13. Ilango SS, Ponnuswamy S, Viswanathan T. Conformational and antimicrobial studies oncertain r-2, c-6-diarylpiperidin-4-ones. Indian Journal of Heterocyclic Chemistry. 2010;20.
  14. McArdle B, Sherwood JN. the Growing of Organic Crystals in Advanced Crystal Growth. New York: Prentice-Hall; 1987.
  15. Lu K, Wei WD, Wang JT. Microhardness and fracture properties of nanocrystal in E Ni-P alloy. Scripta Metallurgia. 1990;24.
  16. Kurtz SK, Perry TT. A Powder Technique for the Evaluation of Nonlinear Optical Materials. Journal of Applied Physics. 1968;39(8).

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Volume 3, Issue 1, Year 2021

Published 2021-01-05

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How to Cite

V, M., S.S., I., & S, P. (2021). Growth, optical, spectral, thermal and mechanical investigations of organic NLO crystal cis-2, 6-bis(4-chlorophenyl)-3, 3-dimethylpiperidin-4-one. Bulletin of Scientific Research, 3(1), 13–20. https://doi.org/10.34256/bsr2112